Refractory Bricks

Classification of Mullite Refractories

Jun 24,2025

I. Classification by Application and Shape

1. Mullite Castings

Properties: Mullite is used as a filler or main component and is produced by casting. It is suitable for lining furnaces with complex shapes (e.g., curved surfaces).

Applications: Lining of high-temperature equipment such as metallurgical furnaces, cement kilns, and glass furnaces.

2. Properties of Mullite Ceramic Products:

The main crystal phase is mullite.

Mullite is divided into ordinary mullite porcelain (with an impure glass phase) and high-purity mullite porcelain (without a glass phase).

The flexural strength of high-purity products reaches 570 MPa at 1300 °C, and the impact toughness is improved by 1.6 times. Applications: High-temperature furnace equipment (trays, shelves), thermocouple protection tubes, crucibles, etc.

II. Density Classification

1. Light Mullite Bricks:

High porosity (low density)

Low thermal conductivity, excellent energy savings

Manufacturing Process:

Additive firing (main process): After firing, sawdust/polystyrene is added to form pores.

Foaming Process: Liquid foam, created using a blowing agent, is poured in. Complex but high-quality process.

Applications: Insulating layer for hot-air furnaces, glass crucibles, ceramic tunnel kilns, etc.

2. Heavy mullite bricks

Properties:

High density (bulk density ≥ 2.65 g/cm³)

Fire resistance > 1790 °C

Fire resistance under load 1600–1700 °C

Excellent thermal shock resistance

Classification:

Sintered mullite bricks: Mainly made of high-alumina clinker, high strength

Fused mullite bricks: Produced by the electric smelting process, large particles, excellent thermal resistance

Applications: Furnace linings with direct flame contact (oil cracking furnaces, metallurgical blast furnaces, etc.)

III. Classification by Operating Temperature Type 1350:

Heat-resistant basic type Type 1450:

For medium and high temperatures Type 1550:

High-temperature type (Al₂O₃ content 71.8%–77.3%)

IV. Classification of Composite Materials

1. Mullite-Corundum Material

Combines the high hardness of corundum with the heat resistance of mullite.

Applications: Ladle covers, desulfurization gun linings

2. Mullite-Silicon Carbide Material

Silicon carbide improves wear resistance and thermal conductivity.

Applications: Highly stressed furnace parts

3. Mullite-Magnesium-Aluminum-Spinel Material

Spinel introduces microcracks into the structure, significantly improving heat resistance.

*Summary of Key Benefits

With its high heat resistance of over 1800°C, it is suitable for industries such as metallurgy, ceramics, glass, and cement.

With its extremely low coefficient of thermal expansion (4.5 × 10⁻⁶/℃), it is suitable for high-temperature precision parts.

Excellent heat resistance (rapid cooling and rapid heating up to 100 times). Suitable for parts such as furnace doors and viewing windows.


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